Download e-book for kindle: Compounds of Transition Metals: Covering the Literature from by Michael Dub (auth.), Michael Dub (eds.)

By Michael Dub (auth.), Michael Dub (eds.)

ISBN-10: 3642521010

ISBN-13: 9783642521010

ISBN-10: 3642521037

ISBN-13: 9783642521034

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Extra info for Compounds of Transition Metals: Covering the Literature from 1937 to 1964

Sample text

BuLi by electrolysis- anodic deposit of (CsHs)2TiCl (1264). CsHsNa- (CsHs)3Ti (683). Cl in CCl4 at 55-60° or in CH2Cl2 at reflux - CsHsTiCl3 (141, 950, 1345, 1785) and chlorinated cyclopentane and cyclopentene (1785). t. or with heating - CsHs(CsHsC12)TiCl2 (608, 723) and CsHs(CsHsCl4)TiCl 2 (6o8). Br in CCl4 at 55-60° - CsHsTiBrCl2 and CsHsBrs (1785). t. - CsHsTiBr3 (950) and CsHsTiBrCl2 (1345). Dry HX (X= halogen) - CsHs(CsH7CsH4)TiX2 (459, 1522). Dild. HCl in Jones reductor- (CsHs)2TiCl (861).

Sol. in common solvents, "sandwich" structure proposed (80). TTBond character with some ionic prop. observed (1173). Valence state of the Ti atom (595, 806). Electronic structure (254). Droh electron configuration (573), The charge on the Ti and C atoms calcd. (1532). Polarographic data (979). + Rxn. with: Dild. HCl or HaS04- [(CsHs) 2 TiOH] (80). CC1 4 - red soln. with a black ppt. (So). FeCl2 - [(CsHs)2Tirr, was further oxidized by aq. acids contg. HNOs to the yellow [(CsHs)aTiOHY (80). cs2 -instantaneous rxn.

With CsHe in CaHe in the presence of Et3N or Py at 75°, 80% yield {460, 831, see also 1523). : b2-3 145-150° (460, 831). Rxn. with: Cl in CCl4 ~ (CsHsTiC13)2 (726). RC02Na ~ CsHs(Bu0)2Ti02CR (1147). Use: Antiknock agent (839) and combustion enhancer (613, 971). : from (Bu0)4Ti by the rxn. with C5 HsMgBr (1:1) in Et20-MePh at reflux, followed by a treatment with TiBr 4 (458, 1807). s 136-145° (458, 1807). Rxn. with: Aq. H2S04 or moist air ~polymeric matl. (458, 1807). (CH20H) 2 in BuOH, upon evapn.

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Compounds of Transition Metals: Covering the Literature from 1937 to 1964 by Michael Dub (auth.), Michael Dub (eds.)


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